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Brewster Lab Publications

Publications from University of Memphis

26. Taylor, N.S.; Suhagia, T.; Pinto, D.D.; Young, K.J.; DeYonker, N.J.; Brewster, T.P.* “Use of 195Pt NMR Chemical Shift as an Electronic Parameter for Bisphosphinemonoxide Ligands” In Review.

25. Taylor, N.S.; Gordinier, M.T.; Suhagia, T. Pinto, D.D.; Cherry, D.D.; Verry, D.S.; Baker, L.N.; DeYonker, N.J.; Young, K.J.*; Brewster, T.P.* “Donor Ability of Bisphosphinemonoxide Ligands Relevant to Late-Metal Olefin Polymerization Catalysis” Inorg. Chem. 2024, Article ASAP. 

24. Charles III, R.M.; Brewster, T.P.* "Chemical Transformations in Heterobimetallic Complexes Facilitated by the Second Coordination Sphere" In: Topics in Organometallic Chemistry. Springer, Berlin, Heidelberg. 2023.

23. Charles III, R.M.; Brewster, T.P. "H2 and Carbon-Heteroatom Bond Activation Mediated by Polarized Heterobimetallic Complexes" (Review Article) Coord. Chem. Rev. 2021, 433, 213765.

22. Yao, W.; DeRegnaucourt, A.; Shrewsbury, E.D.; Loadholt, K.H.; Silprakob, W.; Brewster, T.P.*; Papish, E.T* "Reinvestigating Catalytic Alcohol Dehydrogenation with an Iridium Dihydroxybipyridine Catalyst" Organometallics, 2020, 39, 3656-3652.

21. Charles III, R.M.;+ Taylor, N.S.;+ Mercado, A.A.; Frost, C.; Yokley, T.W.; Schley, N.D.; Eckenhoff, W.T.; DeYonker, N.J.; Brewster, T.P.* "Systematic Evaluation of the Electronic Effect of Aluminum-Containing Ligands in Iridium-Aluminum and Rhodium-Aluminum Bimetallic Complexes" Dalton Trans. 2020, 49, 13029-13043. (+These authors contributed equally to the work)

20. Yokley, T.W.; Tupkar, H.; Schley, N.D.; DeYonker, N.J.; Brewster, T.P.* "CO2 Capture by 2-(Methylamino)pyridine Ligated Aluminum Alkyl Complexes" Eur. J. Inorg. Chem. 2020, 2020 (31), 2958-2967.

19. Charles III, R.M.; Tupkar, H.; Helland, S.D.; Mercado, A.A.; Eckenhoff, W.T.; Schley, N.D.; DeYonker, N.J.; Brewster, T.P.* "Synthesis and Electronic Characterization of Iridium-Aluminum and Rhodium-Aluminum Heterobimetallic Complexes Bridged by 3-Hydroxypyridine and 4-Hydroxypyridine" Eur. J. Inorg. Chem. 2020, 2020 (13), 1192-1198. 

18. Yokley, T.W.; Schley, N.D.; Brewster, T.P.* "Rhodium and Iridium NNO-Scorpionate Complexes:  Synthesis, Structure, and Reactivity with Aluminum Alkyls" Inorg. Chim. Acta 2020, 506, 119529.  (Invited paper to special issue honoring Prof. Tara Dasgupta)

17. Charles III, R.M.; Yokley, T.W.; Schley, N.D.; DeYonker, N.J.; Brewster, T.P.* "Hydrogen Activation and Hydrogenolysis Facilitated By Late Transition Metal-Aluminum Heterobimetallic Complexes" Inorg. Chem. 2019, 58, 12635-12645.

16.  Li, Z.; Yokley, T.W.; Tran, S.L.; Zong, J.; Schley, N.D.; Brewster, T.P.* "Synthesis and Characterization of Rhodium-Aluminum Heterobimetallic Complexes Tethered by 1,3-Bis(diphenylphosphino)-2-propanoxy Group" Dalton Trans. 2019, 48, 8782-8790.

15.  Brewster, T.P.*; Nguyen, T.H.; Li, Z.; Eckenhoff, W.T.; Schley, N.D.; DeYonker, N.J. "Synthesis and Characterization of Heterobimetallic Iridium-Aluminum and Rhodium-Aluminum Complexes" Inorg. Chem. 2018, 57, 1148-1157.

Dr. Brewster's Previous Publications

14. Brewster, T.P.; Rezayee, N.M.; Culakova, Z.; Sanford, M.S.; Goldberg, K.I., "Base Free Iridium-Catalyzed Hydrogenation of Esters and Lactones" ACS Catal. 2016, 6, 6302-6305

13. Brewster, T.P.; Tran, J.C.; Heinekey, D.M.; Goldberg, K.I., "High Catalytic Efficiency Combined with High Selectivity for the Aldehyde-Water Shift using (para-cymene) Ruthenium Catalysts" ACS Catal. 2016, 6, 3113-3117.

12. Brewster, T.P.; Ou, W.C.; Tran, J.C.; Goldberg, K.I.; Hanson, S.K.; Cundari, T.R.; Heinekey, D.M., "Iridium, Rhodium, and Ruthenium Catalysts for the 'Aldehyde-Water Shift' Reaction" ACS Catal. 2014, 4, 3034-3038.

11. Goldberg, K.I.; Heinekey, D.M.; Mayer, J.M.; Miller, A.J.M.; Brewster, T.P. (University of Washington). "Hydrogenation and Disproportionation Catalysis" International Patent WO2014/130714 A1, August 28, 2014.

10. Campos, J.; Hintermair, U.; Brewster, T.P.; Takase, M.K.; Crabtree, R.H., "Catalyst Activation by Loss of Cyclopentadienyl Ligands in Hydrogen Transfer Catalysis with Cp*IrIII Complexes" ACS Catal. 2014, 4, 973-985.

9. Hintermair, U.; Campos, J.; Brewster, T.P.; Pratt, L.M.; Schley, N.D.; Incarvito, C.D.; Crabtree, R.H. "Hydrogen-Transfer Catalysis with Cp*IrIII Complexes: The Influence of the Ancillary Ligands" ACS Catal. 2014, 4, 99-108.

8. Brewster, T.P.; Miller, A.J.M.; Heinekey, D.M.; Goldberg, K.I. "Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium, Rhodium, and Ruthenium" J. Am. Chem. Soc. 2013, 135, 16022-16025.

7. Brewster, T.P.; Konezny, S.J.; Sheehan, S.W.; Martini, L.A.; Schmuttenmaer, C.A.; Batista, V.S.; Crabtree, R.H. "Hydroxamate Anchors for Improved Photoconversion in Dye-Sensitized Solar Cells" Inorg. Chem. 2013, 52, 6752-6764.
*Highlighted in ACS Select Virtual Issue on Inorganic Chemistry Driving the Energy Sciences: Berlinguette, C.P. Inorg. Chem. 2015, 54, 3079-3083.

6. Graeupner, J.; Brewster, T.P.; Blakemore, J.D.; Schley, N.D.; Thomsen, J.M.; Brudvig, G.W.; Hazari, N.; Crabtree, R.H. "Electron-Rich CpIr(biphenyl-2,2'-diyl Complexes with π-Accepting Carbon Donor Ligands" Organometallics 2012, 31, 7158–7164.

5. Parent, A.R.; Brewster, T.P.; De Wolff, W.; Crabtree, R.H.; Brudvig, G.W. "Sodium Periodate as a Primary Oxidant for Water-Oxidation Catalysts" Inorg. Chem. 2012, 51, 6147-6152.

4. Brewster, T.P.; Ding, W.; Schley, N.D.; Hazari, N.; Batista, V.S.; Crabtree, R.H. "Thiocyanate Linkage Isomerism in a Ruthenium Polypyridyl Complex" Inorg. Chem. 2011, 50, 11938–11946.

3. Brewster, T.P.; Blakemore, J.D.; Schley, N.D.; Incarvito, C.D.; Hazari, N.; Brudvig, G.W.; Crabtree, R.H. "An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+ Related to a Water Oxidation Catalyst" Organometallics 2011, 30, 965-973.

2. Ley, A.N.; Dunaway, L.E.; Brewster, T.P.; Dembo, M.D.; Harris, T.D.; Baril-Robert, F.; Li, X.; Patterson, H.H.; Pike, R.D. "Reversible Luminescent Reaction of Amines with Copper(I) Cyanide" Chem. Commun. 2010, 46, 4565-4567.

1. Bayse, C.A.; Brewster, T.P.; Pike, R.D. "Photoluminescence of 1-D Copper(I) Cyanide Chains: A Theoretical Description" Inorg. Chem. 2009, 48, 174-182.